Hydroxypropyl methylcellulose (HPMC) is a polymer compound obtained by chemically modifying natural plant cellulose. It has good water solubility, non-toxicity, odorlessness and good biocompatibility. Therefore, it is widely used in paint, construction, pharmaceuticals, food and other fields. In the paint industry, HPMC plays a vital role as a thickener, which can improve the performance, stability and processing technology of paint.
1. The role of HPMC as a paint thickener
HPMC plays the following roles as a thickener in paint:
(1) Increase the viscosity of the paint
HPMC can absorb water and swell in water-based paints mainly through its polymer chain structure, increase the interaction between molecules, and thus increase the viscosity of the paint. The increase in viscosity improves the rheological properties of the paint and enhances the coating performance of the paint. Specifically, HPMC can make the brushing and spraying performance of the paint smoother and avoid excessive sagging or dripping.
(2) Improve the rheological properties of coatings
The application of HPMC in coatings can significantly improve their rheological properties, especially at high concentrations and low shear rates, and can maintain good viscosity and stability. This is very important for the processing of coatings under different process conditions, especially for the construction effect when brushing on large areas. By adjusting the concentration and molecular weight of HPMC, the fluidity of the coating can be regulated, so that it is not easy to flow too fast during use, and can maintain suitable construction properties.
(3) Improve the horizontal spreading of coatings
The thickening effect of HPMC in coatings is not only to increase viscosity, but also to improve the leveling of coatings. Horizontal spreading refers to the ability of the coating to be evenly distributed on the surface of the substrate after brushing without causing mottled or uneven phenomena. HPMC increases the surface tension and optimizes the flow characteristics of the coating, so that the coating forms a uniform and smooth coating film on the surface of the substrate.
(4) Prolong the open time of the coating
As a thickener, HPMC also has the function of prolonging the open time of the coating. The open time refers to the time that the coating remains operable during the application process. Prolonging this time helps to prevent the coating from drying too quickly during the brushing process, which leads to uneven coating or brush marks. HPMC improves the evaporation rate of the coating, allowing the water-based coating to maintain an appropriate viscosity for a longer period of time, ensuring a smoother coating process.
(5) Enhance the stability of the coating
The thickening effect of HPMC also helps to enhance the dispersion stability of the coating, especially in the water-based coating system, it can stabilize solid particles such as pigments and fillers, prevent sedimentation, and extend the storage period of the coating. By adjusting the molecular weight and degree of substitution of HPMC, the stability of the coating can be optimized so that it will not stratify or precipitate during long-term storage.
2. Application of HPMC in water-based coatings
Water-based coatings have been widely promoted in recent years due to their environmental protection, non-toxicity, and low pollution. The application of HPMC in water-based coatings is particularly important. It not only acts as a thickener, but also plays an important role in the following aspects:
(1) Improve fluidity and workability
The fluidity of water-based coatings is often affected by the water content and solid content. HPMC can adjust the rheology of water-based coatings to maintain a higher viscosity at low shear rates, thereby ensuring that the coating has good workability during coating. In addition, HPMC can also optimize the thixotropy of the coating, that is, the coating has a certain viscosity in a static state, but can quickly reduce the viscosity during the application process to facilitate flow.
(2) Improve the water resistance of water-based coatings
HPMC molecules contain hydrophilic groups, which can enhance the affinity of water-based coatings for water. During the drying process of the coating, HPMC can effectively reduce the problem of coating cracking caused by rapid evaporation of water, thereby improving the water resistance and adhesion of the coating.
(3) Enhance the transparency and gloss of the coating
Due to its high solubility, HPMC can help water-based coatings maintain high transparency and gloss. In some special coating applications, such as varnishes and clear coatings, the use of HPMC can maintain the clarity of the coating and improve the gloss of the final coating.
3. Application of HPMC in oil-based coatings
In oil-based coatings, HPMC is mainly used as a thickener and rheology regulator. Although HPMC itself is highly water-soluble, its good thickening effect in oil-based coatings is still widely used. In oil-based paints, HPMC can effectively adjust the viscosity of the paint, improve the brushability and sprayability of the paint, and also improve the stability of the paint, prevent pigment sedimentation, and reduce the stratification of the paint.
4. Advantages of HPMC as a thickener
Compared with traditional thickeners, the application of HPMC in paints has the following significant advantages:
Good environmental protection: HPMC is a derivative of natural cellulose and does not contain harmful substances, so it is safer to use in paints and does not pollute the environment.
Strong water solubility: HPMC has good solubility and stability in water-based paints, can provide ideal thickening effects, and will not affect other properties of the paint.
Excellent construction performance: HPMC can effectively improve the construction performance of the paint, avoid premature drying and uneven coating, and is suitable for different coating process requirements.
Improve storage stability: HPMC can stabilize the physical and chemical properties of the paint and reduce the precipitation phenomenon that may occur during storage.
As a paint thickener, HPMC can not only increase the viscosity of the paint and improve the rheology, but also enhance the stability, leveling and construction performance of the paint. It is widely used in water-based paints and oil-based paints. By adjusting its molecular structure and concentration, the performance of the coating can be flexibly adjusted to meet the production needs of different types of coatings. With the increasing demand for environmentally friendly and low-pollution coatings, the application prospects of HPMC will be broader and it will become one of the key functional additives in the coatings industry.
Post time: Feb-15-2025